Hazard search

PMDI

CAS number
9016-87-9
Also known as
PAPI · Polymeric MDI · Polymeric(methylene bisphenyl isocyanate) · Polymethylene polyphenyl polyisocyanate

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 0.02 mg/m³
15-minute STEL 0.07 mg/m³

Notations

  • Sen: can cause sensitisation

Sampling methods

MethodSamplingMedium AnalysisPart numbers
MDHS 25/4
Organic Isocyanates in air (aerosols) by HPLC -EC
Method document (opens in a new tab)
Active (pump) Midget impinger & coated glass fibre filter 225-36-4
225-22
MDHS 25/4
Organic Isocyanates in air (vapours only) by HPLC -EC
Method document (opens in a new tab)
Active (pump) Stainless Steel IOM with coated glass fibre filter 225-79A
MDHS 25/4
Organic Isocyanates in air (aerosols per Appendix 2) by HPLC -EC
Method document (opens in a new tab)
Active (pump) Stainless Steel IOM with coated glass fibre filter(s) 225-79A
OSHA 5002
Organic Vapour Sampling Group 3-diisocyanates- by UHPLC-FD
Method document (opens in a new tab)
Active (pump) Glass fibre filter & support pad in open-face cassette HPLC-UV or HPLC-FD 225-9002
225-9013
225-5
OSHA 5002
Organic Vapour Sampling Group 3 by UHPLC-FLR
Method document (opens in a new tab)
Active (pump) Open-face cassette with Glass Fibre Filter & support pad (page 2 of method) 225-3250
225-7
225-27

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)