Hazard search

Phosphine

CAS number
7803-51-2
Also known as
Hydrogen phosphide · Phosphorus trihydride

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 0.1 ppm
8-hour TWA 0.14 mg/m³
15-minute STEL 0.2 ppm
15-minute STEL 0.28 mg/m³

Sampling methods

MethodSamplingMedium AnalysisPart numbers
NIOSH 6002
Phosphine by UV-VIS
Method document (opens in a new tab)
Active (pump) Coated silica gel tube (300/150mg) UV-VIS 226-165A
224-29B
OSHA 1003
Phosphine by ICP -AES
Method document (opens in a new tab)
Active (pump) Coated filter in preloaded cassette ICP-AES 225-9018
225-1
Non-agency
Phosphine by Colorimetric analysis
Direct-reading Gastec detector tube 810-7

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)