Hazard search

Hydrogen fluoride

CAS number
7664-39-3
Also known as
Hydrofluoric acid · Hydrofluoric acid (fluorides) · Hydrogen fluoride (as F) · Hydrogen fluoride (fluorides)

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 1.8 ppm
8-hour TWA 1.5 mg/m³
15-minute STEL 3 ppm
15-minute STEL 2.5 mg/m³

Sampling methods

MethodSamplingMedium AnalysisPart numbers
NIOSH 7902
Fluorides by ISE
Method document (opens in a new tab)
Active (pump) Treated 0.8µm MCE filter in cassette ISE 225-9001
225-1
NIOSH 7906
Fluorides by IC
Method document (opens in a new tab)
Active (pump) Treated 0.8µm MCE filter in cassette IC-CD 225-9031
225-1
OSHA ID 110 Active (pump) ISE 225-9001
225-1
OSHA ID-110
Fluoride (F & HF) by ISE
Method document (opens in a new tab)
Active (pump) Treated 0.8µm MCE filter in cassette 225-9001
225-1
Non-agency
Hydrogen fluoride by Colorimetric analysis
Direct-reading Gastec detector tube 810-17
810-17L
810-17LL
Non-agency
Hydrogen fluoride by Colorimetric analysis
Passive Gastec Dosi-tube 810-17D
810-14D
Other Passive DR 810-14D
Other Passive DR 810-17D
Other Contact SKC Active (pump) ISE 225-70A
225-1930

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)