Hazard search

Formic acid

CAS number
64-18-6
Also known as
Methanoic acid

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 5 ppm
8-hour TWA 9.6 mg/m³

Sampling methods

MethodSamplingMedium AnalysisPart numbers
NIOSH 2011
Formic acid by IC
Method document (opens in a new tab)
Active (pump) PTFE filter (5µm) with Silica gel tube (400/200mg) IC-CD 225-1728A
225-3-25LF
226-10-03
225-1
Non-agency
Formic acid by Colorimetric analysis
Direct-reading Gastec detector tube 810-81
810-81L
Non-agency
Formic acid by Colorimetric analysis
Passive Gastec Dosi-tube 810-81D
Non-agency
Acetic acid and formic acid by IC /CD
Method document (opens in a new tab)
Passive Passive sampler 500-200
Other Passive IC/CD 500-200
Other Passive DR 810-81D

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)