Hazard search

Styrene

CAS number
100-42-5
Also known as
Ethenylbenzene · Phenylethylene · Styrene (phenylethylene) · Styrene (phenylethylene) (Hydrocarbons, Aromatic) · Styrene (phenylethylene) (see online Passive Sampling Guide) · Vinylbenzene

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 100 ppm
8-hour TWA 430 mg/m³
15-minute STEL 250 ppm
15-minute STEL 1080 mg/m³

Sampling methods

MethodSamplingMedium AnalysisPart numbers
MDHS 72
VOCs by thermal desorption and GC
Method document (opens in a new tab)
Active (pump) Tenax thermal desorption tube (250mg) TD, GC 226-357
MDHS 80 Active (pump) TD, GC 226-357
MDHS 88
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Passive Passive sampler GC-FID 575-002
575-006
MDHS 96
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Active (pump) Charcoal tube (100/50mg) GC-FID 226-01
MDHS 104
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Active (pump) Charcoal tube (100/50mg) 226-01
MDHS 104
VOCs by thermal desorption and GC
Method document (opens in a new tab)
Active (pump) Tenax TD tube (250mg) 226-357
NIOSH 1501
Hydrocarbons (aromatic) by GC-FID
Method document (opens in a new tab)
Active (pump) Charcoal tube (100/50mg) GC-FID 226-01
OSHA 89
Divinyl benzene, Ethylvinyl benzene & Styrene by GC-FID
Method document (opens in a new tab)
Active (pump) Coated charcoal tube (100/50mg) GC-FID 226-73
OSHA 1014
Styrene by GC-FID
Method document (opens in a new tab)
Passive Passive sampler HPLC-UV 575-006
ASTM D5466
VOCs by GC -MS
Method document (opens in a new tab)
Active (pump) Canister GC-MS
EPA TO-17 Active (pump) TD, GC 226-350
226-347
224-26-02
224-26-CPC
EPA TO-17
VOCs by thermal desorption and GC
Method document (opens in a new tab)
Active (pump) Two Thermal Desorption tubes
EPA TO-17
Toxic Organic Compounds by thermal desorption and GC
Method document (opens in a new tab)
Passive Passive sampler
Non-agency
Vinyl benzene by Colorimetric analysis
Direct-reading Gastec detector tube 810-124
810-124L
810-153
Non-agency
VOCs by solvent extraction and GC
Method document (opens in a new tab)
Passive Anasorb CSC (500mg) passive sampler 690-105
Non-agency
VOCs by thermal desorption and GC
Method document (opens in a new tab)
Passive Anasorb GBC1 (370mg) or Chromosorb 106 (285 mg) or Tenax TA (265 mg) passive sampler 690-101
690-103
690-104
Non-agency
Styrene by Colorimetric analysis
Passive Gastec Dosi-tube 810-122DL
Non-agency 54 Active (pump) GC-FID 226-81A
Other Passive GC-FID 575-002
Other Passive GC-FID 575-006
Other Passive TD, GC 690-101
690-103
690-104
Other Passive GC-FID 690-105
Other Passive DR 810-122DL
Other Internal Passive TD, GC 690-101
690-103
690-104
Other Internal Passive GC-FID 690-105

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)