Hazard search

Methyl chloride

CAS number
74-87-3
Also known as
Chloromethane · Chloromethane (methylchloride) · Methyl chloride (Chloromethane) · Monochloromethane

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 50 ppm
8-hour TWA 105 mg/m³
15-minute STEL 100 ppm
15-minute STEL 210 mg/m³

Sampling methods

MethodSamplingMedium AnalysisPart numbers
MDHS 96
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Active (pump) Two charcoal tubes in series (front 400/200mg, back 100/50mg) GC-FID 226-09
226-01
MDHS 104
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Active (pump) Two charcoal tubes in series (front 400/200mg, back 100/50mg) 226-09
226-01
NIOSH 1001
Methyl chloride by GC-FID
Method document (opens in a new tab)
Active (pump) Two charcoal tubes in series (front 400/200mg, back 100/50mg) GC-FID 226-09
226-01
ASTM D 5466 GC-MS
Non-agency
Methyl chloride by Colorimetric analysis
Direct-reading Gastec detector tube 810-51
810-51L
Non-agency
VOCs by solvent desorption and GC-FID
Method document (opens in a new tab)
Passive Passive sampler 575-001
575-002
Other Passive GC-FID 575-001
575-002

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)