Hazard search

Benzyl chloride

CAS number
100-44-7
Also known as
(Chloromethyl)benzene · Benzyl chloride (hydrocarbons, halogenated) · α-Chlorotoluene

UK workplace exposure limits

LimitValueApplies to
8-hour TWA 0.5 ppm
8-hour TWA 2.6 mg/m³
15-minute STEL 1.5 ppm
15-minute STEL 7.9 mg/m³

Notations

  • Carc: carcinogen

Sampling methods

MethodSamplingMedium AnalysisPart numbers
MDHS 88
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Passive Passive sampler GC-FID 575-001
575-002
MDHS 96
VOCs by solvent desorption and GC
Method document (opens in a new tab)
Active (pump) Charcoal tube (100/50mg) GC-FID 226-01
MDHS 104
VOCs by solvent or thermal desorption and GC
Method document (opens in a new tab)
Active (pump) Charcoal tube (100/50mg) 226-01
NIOSH 1003
Halogenated hydrocarbons by GC-FID
Method document (opens in a new tab)
Active (pump) Charcoal tube (100/50mg) GC-FID 226-01
ASTM D5466
VOCs by GC -MS
Method document (opens in a new tab)
Active (pump) Canister GC-MS
Non-agency
Benzyl chloride by Colorimetric analysis
Direct-reading Gastec detector tube 810-132L
Other Passive GC-FID 575-001
Other Passive GC-FID 575-002

Methods and limits as published by their agencies and summarised by SKC; check the current method and the limit that applies to you before sampling.

Source: SKC Ltd (UK), Hazard Search, used with SKC's permission (opens in a new tab); SKC Inc. (USA), Sampling Guides, used with SKC's permission (opens in a new tab)